A research team from the University of Chemistry and Technology, Prague (UCT Prague) and the Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences (IOCB Prague) has created and described a new type of photoswitch. The molecule, a thienyl-based acylhydrazone, undergoes an unprecedented “closed-to-open-shell” transformation, where light converts it into a stable diradical.



Summary

Researchers at UCT Prague and IOCB Prague have developed a novel photoswitch based on a thienyl-based acylhydrazone molecule. This innovative molecule uniquely transforms from a closed-shell structure to a stable diradical when exposed to light. This “closed-to-open-shell” transformation represents a significant advancement in photoswitch technology, offering potential applications in various fields due to the creation of a stable diradical state through light exposure. This could lead to the development of new materials and technologies that leverage the unique properties of light-induced diradicals.

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